By M. Khare
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Additional resources for Air Pollution - Monitoring, Mdlg., Health and Control
The substituted arsines are trivalent organic arsenical compounds which, depending on the number of alkyl or phenyl groups that they have attached to the arsenic nucleus, are known as mono-, di- or tri-substituted arsines. Dichloroethylarsine (C2H5AsCl2), or ethyldichloroarsine, is a colourless liquid with an irritant odour. This compound was developed as a potential chemical warfare agent. Dichloro(2-chlorovinyl-) arsine (ClCH:CHAsCl2), or chlorovinyldichloroarsine (lewisite), is 32 Air Pollution – Monitoring, Modelling, Health and Control an olive-green liquid with a germanium-like odour.
Of lesser industrial importance are cyanides, nitrides, nitrates, phosphides, phosphates and iron carbonyl. 1 Toxicity Industrial dangers are present during the mining, transportation and preparation of the ores, during the production and use of the metal and alloys in iron and steel works and in foundries, and during the manufacture and use of certain compounds. Inhalation of iron dust or fumes occurs in iron-ore mining; arc welding; metal grinding, polishing and working; and in boiler scaling.
Elimination of cadmium is very slow. As a result of this, cadmium accumulates in the body, the concentrations increasing with age and length of exposure (62). Based on organ concentration at different ages the biological half-life of cadmium in humans has been estimated in the range of 7 to 30 years. 2 Acute toxicity Inhalation of cadmium compounds at concentrations above 1 mg Cd/m3 in air for 8 hours, or at higher concentrations for shorter periods, may lead to chemical pneumonitis, and in severe cases pulmonary oedema.
Air Pollution - Monitoring, Mdlg., Health and Control by M. Khare