By Carey F., Sundberg R.
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Extra resources for Advanced Organic Chemistry. Structure and Mechanisms
G. 2 Direct and indirect industrial preparations of a compound A. 6 includes an account of how kinetically useful information may be obtained by good monitoring under controlled reaction conditions (especially temperature). 4 and Chapter 9). g. 4. A note of caution is also warranted. It is well established that reaction mechanisms depend on structures of reactants, so extrapolation of mechanistic deductions from one reaction to another of a ‘similar’ reactant should not be automatic. g. acid, base, water or metal ions (see Chapter 11).
Wiley-VCH, Weinheim, Germany, p. 317. 24. Gerson, F. and Huber, W. (2003) Electron Spin Resonance Spectroscopy of Organic Radicals. WileyVCH, Weinheim, Germany. 25. Moad, G. H. (1995) The Chemistry of Free Radical Polymerization. Pergamon, Bath. 26. A. P. (1972) Chemical Reviews, 72, 705. 27. , Sakai, M. and Miyaura, N. (1998) Journal of the American Chemical Society, 120, 5579. 28. html. Chapter 2 Investigation of Reaction Mechanisms by Product Studies T. W. 1 Introduction and overview – why study organic reaction mechanisms?
The GC-MS study also identiﬁed undeuterated dichloronorbornanes amongst the products . 15, a thermodynamically controlled process (discovered serendipitously) . Molecular mechanics calculations indicated that the slow step of the rearrangement could occur prior to formation of exo-41, which rearranges in a few minutes to 40 on treatment with AlBr3 in CS2 at 25◦ C. When the reaction of exo-41 was conducted at −10◦ C and monitored by GC over a period of 100 minutes, the presence of two additional intermediates (42 and 43) was revealed .
Advanced Organic Chemistry. Structure and Mechanisms by Carey F., Sundberg R.