Download PDF by Carey F., Sundberg R.: Advanced Organic Chemistry. Reactions and Synthesis

By Carey F., Sundberg R.

ISBN-10: 0306462443

ISBN-13: 9780306462443

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Komeshima, K. Koga, J. Chem. , Chem. Commun. 1979, 437; (b) H. Takemura, N. Komeshima, I. Takahashi, S. Hashimoto, N. Ikota, K. Tomioka, K. Koga, Tetrahedron Lett. 1987, 28, 5687. [2] (a) D. A. Evans, J. S. Johnson, Diels-Alder Reaction, in: Comprehensive Asymmetric Catalysis, Vol. III, E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds), Springer, New York, 1999, p 1177; (b) H. B. Kagan, O. Riant, Chem. Rev. 1992, 92, 1007; (c) K. Narasaka, Synthesis 1991, 1; (d) K. Maruoka, H. Yamamoto, Asymmetric Reactions with Chiral Lewis Acid Cata- lysts, in: Catalytic Asymmetric Synthesis, I.

The catalyst 20 was prepared from bis(oxazoline) and magnesium iodide in the presence of I2 to remove iodide. Other bis(oxazoline)-magnesium catalysts have been intensively investigated by Desimoni et al. [31], who prepared them from three different bis(oxazolines) and magnesium perchlorate or triflate. Although the catalyst 21, with the perchlorate anion, gave the 2S adduct in moderate optical purity (72% ee) on reaction of acryloyl derivative and cyclopentadiene, the opposite enantiomer (2R, 70% ee) was obtained by adding 2 equiv.

Hashimoto, N. Ikota, K. Tomioka, K. Koga, Tetrahedron Lett. 1987, 28, 5687. [2] (a) D. A. Evans, J. S. Johnson, Diels-Alder Reaction, in: Comprehensive Asymmetric Catalysis, Vol. III, E. N. Jacobsen, A. Pfaltz, H. Yamamoto (Eds), Springer, New York, 1999, p 1177; (b) H. B. Kagan, O. Riant, Chem. Rev. 1992, 92, 1007; (c) K. Narasaka, Synthesis 1991, 1; (d) K. Maruoka, H. Yamamoto, Asymmetric Reactions with Chiral Lewis Acid Cata- lysts, in: Catalytic Asymmetric Synthesis, I. ), VCH, New York, 1993, p 413; (e) R.

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