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ISBN-10: 0470771585

ISBN-13: 9780470771587

ISBN-10: 0471996106

ISBN-13: 9780471996101

Chapter 1 fresh advances within the theoretical remedy of acid derivatives (pages 1–58): I. G. Csizmadia, M. R. Peterson, C. Kozmutza and M. A. Robb
Chapter 2 Thermochemistry of acid derivatives (pages 59–66): Robert Shaw
Chapter three Chiroptical houses of acid derivatives (pages 67–120): Rolf Hakansson
Chapter four Mass spectra of acid derivatives (pages 121–174): S. W. Tam
Chapter five Complexes of acid anhydrides (pages 175–212): R. Foster
Chapter 6 Hydrogen bonding in carboxylic acids and derivatives (pages 213–266): Dusan Hadzi and Snegulka Detoni
Chapter 7 The synthesis of carboxylic acids and esters and their derivatives (pages 267–490): Michael A. Ogliaruso and James F. Wolfe
Chapter eight The chemistry of lactones and lactams (pages 491–531): G. V. Boyd
Chapter nine The chemistry of orthoamides of carboxylic acids and carbonic acid (pages 533–599): W. Kantlehner
Chapter 10 Detection and backbone of acid derivatives (pages 601–640): W. H. Prichard
Chapter eleven The photochemistry of natural acids, esters, anhydrides, lactones and imides (pages 641–753): Richard S. Givens and Nissim Levi

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Additional info for Acid Derivatives: Volume 1 (1979)

Example text

Csizmadia, M. C. Harrison and B. T. Z. T. Quart Progr. Repf.. 50, 4 (1963); Theoret. Chim. Acta, 6,217 (1966). 12. H. Basch, M. B. Robin and N. A. Keubler,J. Chem. Phys.. 49, SO07 (1968). 13. The Koopmans’ theorem ionization potential (IP) is simply the negative of t h e energy of the orbital from which the electron is removed. The absolute valrie of t h e ZP is generally only a crude estimate as the reorganization energy is neglected, but trends are usually reproduced well. 14. W. J. Hehre and J.

R. Peterson, K. Yates and I. G. Csizmadia, Bog. Theorer. Org. , 2, 162 (1977). (150°, 180") (b) h (340", 300") (C) t I I m * I I * I m' * m I @*t > @j * @ m * * @ FIGURE 24. Predicted topology of the conformational energy surface for the tetrahedral-intermediate. A, B and C are low minima. while a. b and c are h k h minima (the conformations arc shown in Figure 23). The Ss are the saddle points, m are low maxima and M is the high maximum. Reproduced with permission from M. H. Lien, A. C. Hopkinson, M.

J. E. Del Bene, R. Ditchfield and J. A. Pople, J. Clrem. , 55, 2236 (1971). 17. R. Ditchfield, J. E. Del Bene and J. A. Pople, J. Amer. Chem. , 94, 703 (1972). 18. J. Hehre, L. Radom and J. A. Pople. J. Amer. Chem. , 94,1496 (1972). 19. J. A. Pople and hl. S. Gordon, J. Amer. Chem. , 89, 4253 (1967); see also Reference 15. 20. H. Leblanc, Jr, V. W. Laurie and W. Gwinn, J. Chem. , 33,598 (1960). 21. The other structural parameters are determined consistently experimentally - see Table 1 of Reference 11.

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